Subatomic Particles
Atoms are the basic units of matter and are made up of smaller components called subatomic particles. There are many types of subatomic particles known to science, but in the context of basic atomic structure, only three are considered most important: electrons, protons and neutrons. These three particles differ in their location, charge and mass.
Together, electrons, protons and neutrons form the complete structure of atoms. Their arrangement and interaction define the atom's properties, chemical behavior, and participation in physical and chemical processes. These subatomic particles laid the foundation of modern atomic theory and quantum chemistry.
1. Electron
Electrons are negatively charged subatomic particles. They are extremely small in mass and are found outside the nucleus of the atom in specific regions called orbitals or shells. The charge of an electron is −1 and its mass is approximately 1/1836 of a proton or neutron, which is around 9.1 × 10⁻³¹ kg, meaning it is nearly negligible in terms of atomic mass.
The electron was discovered by J.J. Thomson in 1897 during his experiments with cathode ray tubes. He showed that cathode rays are made of negatively charged particles, which were later named electrons. His discovery was the first evidence that atoms are not indivisible and contain internal structure.
In a neutral atom, the number of electrons is always equal to the number of protons so that their opposite charges cancel each other out, making the atom electrically neutral. Electrons play a major role in chemical bonding and reactions because they are involved in gaining, losing, or sharing during interactions with other atoms.
Electrons can also behave as Beta (β⁻) particles in radioactive decay processes. In such cases, the electron is emitted from the nucleus as a product of nuclear transformation, even though electrons are generally not part of the nucleus.
2. Proton
Protons are positively charged subatomic particles found in the nucleus of an atom. Each proton carries a +1 charge and has a mass of approximately 1.0073 atomic mass units (amu) or 1.6726 × 10⁻²⁷ kg. The number of protons in an atom determines the atomic number, which identifies the type of element. For example, all atoms with one proton are hydrogen atoms.
The proton was discovered by Ernest Rutherford in 1917 during experiments in which he bombarded nitrogen gas with alpha particles. He observed hydrogen nuclei being ejected and concluded that these positively charged particles, which he called protons, are fundamental components of atomic nuclei.
A single proton alone, such as found in a hydrogen nucleus without any neutrons, is often referred to simply as a proton. Protons are relatively stable and do not decay under normal conditions.
Protons also contribute to the mass of an atom and determine its electrical characteristics in combination with electrons.
3. Neutron
Neutrons are neutral subatomic particles, meaning they carry no electric charge. They are found in the nucleus along with protons. Neutrons have a mass slightly greater than protons, roughly 1.0087 amu or 1.6750 × 10⁻²⁷ kg, but this difference is very small.
The neutron was discovered by James Chadwick in 1932. In his experiment, Chadwick bombarded beryllium with alpha particles and detected radiation that had no charge but enough mass to knock protons from paraffin wax. This led to the conclusion that the nucleus contains neutral particles, which he named neutrons.
Neutrons act as a nuclear glue by reducing the repulsion between the positively charged protons in the nucleus. Without neutrons, the protons would repel each other strongly, making the nucleus unstable. The number of neutrons can vary among atoms of the same element, leading to the formation of isotopes.
Balance of Charges in Neutral Atoms
In a neutral (uncharged) atom:
Number of protons = Number of electrons
This balance ensures the atom as a whole does not carry a net electric charge. If this balance is disturbed, the atom becomes an ion.
- If electrons are lost, the atom becomes positively charged (cation).
- If electrons are gained, it becomes negatively charged (anion).
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